Everything about Stepwise Reaction totally explained
A
stepwise reaction is a
chemical reaction with one or more
reaction intermediates and involving at least two consecutive
elementary reactions.
The rate law of an elementary reaction is rather simple. On the other hand, when combining multiple elementary steps, the rate law can become rather complex. Moreover, when speaking about catalytic reactions, the diffusion may also limit the reaction. In general, however, there's one very slow step, which is the rate-determining step, for example the reaction doesn't proceed any faster than the rate-determining step proceeds.
Organic reactions, especially when involving
catalysis, are often stepwise. For example, a typical
enol reaction consists of at least these elementary steps:
- Deprotonation next to (α to) the carbonyl: HC–C=O → C=C–O–
- Attack of enolate: Rδ+ + C=C–O– → R–C–C=O
Rδ+ is an electron acceptor, for example, the carbon of a carbonyl (C=O). A very strong base, usually an alkoxide, is needed for the first step.
Reaction intermediates may be trapped in a
trapping reaction. This proves the stepwise nature of the reaction and the structure of the intermediate. For example,
superacids were used to prove the existence of
carbocations.
Further Information
Get more info on 'Stepwise Reaction'.
|
External Link Exchanges
Do you know how hard it is to get a link from a large encyclopaedia? Well we're different and will prove it. To get a link from us just add the following HTML to your site on a relevant page:
<a href="http://stepwise_reaction.totallyexplained.com">Stepwise reaction Totally Explained</a>
Then simply click through this link from your web page. Our crawlers will verify your link, extract the title of your web page and instantly add a link back to it. If you like you can remove the words Totally Explained and embed the link in article text.
As long as your link remains in place, we'll keep our link to you right here. Please play fair - our crawlers are watching. Your site must be closely related to this one's topic. Any kind of spamming, dubious practises or removing the link will result in your link from us being dropped and, potentially, your whole site being banned. |